We describe nonequilibrium fluctuations of entropy production, heat and
work in classical and quantum mesoscopic systems using the theory of
Martingales, a mathematical framework widely used in finance.
For non-equilibrium steady states, we use martingale theory to study
the statistics of extrema, stopping times and passage probabilities of
entropy production, and show that they are universal for Langevin
processes. In particular, we derive equalities and inequalities for the stopping
and extreme-value statistics of the entropy production and work, and
test these results experimentally with an electronic double dot.
We have recently extended our formalism to Markovian non-stationary
processes. To this aim, we introduce ''gambling demons'' which stop a
nonequilibrium process at a finite time using a customary criterion.
For such demons, the average work done on a small system can be below
the free energy change, a result which challenges the classical second
law of thermodynamics. Our work paves the way towards work extraction
strategies inspired in knowledge in quantitative finance.
[1] I. Neri, E. Roldan, F. Julicher, PRX 7, 011019 (2017)
[2] S. Pigolotti, I. Neri, E. Roldan, F. Julicher, PRL 119(14), 140604 (2017)
[3] R. Chetrite, S. Gupta, I. Neri, E. Roldan, EPL 99, 115422 (2019)
[4] I. Neri, E. Roldan, S. Pigolotti, F. Julicher, J. Stat. Mech. 2019 (10), 104006 (2019)
[5] G. Manzano et. al, arXiv:2008.01630v2 (2020)