11–13 Jun 2014
Albanova University Centre
Europe/Stockholm timezone

Relaxor ferroelectrics as pseudo-Stoner glasses

11 Jun 2014, 10:00
1h
FA32 (Albanova University Centre)

FA32

Albanova University Centre

Speaker

David Sherrington (Rudolf Peierls Centre for Theoretical Physics, University of Oxford, UK)

Description

In 1979 John Hertz introduced the concept of the Stoner Glass to describe spin glass ordering in itinerant transition metal magnetic alloys. Two decades earlier an interesting behaviour (of distinctly frequency-dependent but sharpish peaks in the dynamical permittivity) was observed in some ceramic ionic alloys, now known as relaxor ferroelectrics. They have received a great deal of attention and practical application, but, even over half a century later, their microscopic their underlying physics has remained ill-understood and controversial. In this talk I shall argue that they are actually displacive analogues of John’s Stoner glass, the peaking corresponding to the onset of the quasi-Stoner spin glass phase. Displacive relaxor ferroelectrics have also been shown to exhibit polar nano-regions persisting for measurable times at temperatures higher than those of the permittivity peaks. I shall argue that this behaviour and both the pseudo-Stoner glass and pseudo-Stoner ferro-order can be understood in terms of a mapping to the problem of Anderson localization, analogous to (but extended beyond) one I devised in 1973 to understand the same experimental systems as inspired John, based on a similar disordered Hubbard model to that he used (but with a complementary methodology). Recent experimental measurements corroborate the argument for PNRs. These observations extrapolate to several further suggestions and questions for both relaxors and itinerant spin glasses and the light of new knowledge could stream again through the window that John opened half a lifetime ago. Reference 1. J.A.Hertz: The Stoner Glass; PRB 19, 4796 (1979) 2. D.Sherrington and K.Mihill: Effects of Clustering on the Magnetic Properties of Transition Metal Alloys: J.Physique Colloque 35, C4-199 (1974) 3. D.Sherrington: BZT: A Soft Pseudospin Glass; PRL 111, 227601 (2013) 4. D.Sherrington: Pb(Mg1/3Nb2/3)O3: A minimal induced-moment soft pseudospin glass perspective; PRB 89, 064105 (2014) 5. M.E.Manley et al.: Phonon localization drives polar nanoregions in a relaxor ferroelectric; Nature Comm. 5:3683 DOI:10.1038/ncomms4683 (online April 2014)

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