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Measured evaporative decay of mixed heavy and light water clusters show a remarkable scaling with the deuterium mole fraction above cluster size 8, including across the well-known shell closing at N = 21 with values consistent with macroscopic surfaces. Helmholtz free energy differences of competing channels derived from these distributions take the simplest possible form of a single energy parameter and the deuterium-protium mixing entropy. The results rule out any H-H interaction above the sub-meV scale. Comparison with similar experiments on partially deuterated ammonia clusters emphasize the special properties of water.
DESIREE Group